The enthalpy change for a reaction where activation energy for both forward and reverse reactions is the same value is zero.
Enthalpy change (ΔH) is a measure of the heat absorbed or released during a chemical reaction. It is the difference in the enthalpy of the reactants and products. The activation energy (Ea) is the energy required to overcome the energy barrier between the reactants and products to allow a chemical reaction to occur.
If the activation energy for both the forward and reverse reactions of a chemical process is the same value, it means that the energy required to go from reactants to products is the same as the energy required to go from products to reactants. Therefore, the enthalpy change of the reaction is zero. The enthalpy change of the reaction is given by the difference in the enthalpy of the reactants and products.
ΔH = H(products) - H(reactants)
Therefore, if the activation energy for the forward and reverse reactions is the same, the enthalpy change for the reaction is zero.
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How many moles of Pb3O4 are produced from 1. 25 moles of oxygen? (show explanation/work if possible so I can better understand)
2.5 moles pf pb3O4 are produced from 1.25 moles of oxygen
The reaction is shown below.
6PBo+ O2------> 2 PB3O4
here 1 mole of O2(oxygen) -----> 2 moles PB3O4
1 for 1.2 moles of O2------> ?(x)
x= 1.2* 2/ 1
x= 2.5 moles of PB3O4
As the amount of reactants increases, the molecular distance between the reacting particles decreases, increasing the likelihood of subsequent collisions. The four key variables that influence reaction rate are reactant concentration, the reactants' physical state, surface area, temperature, and the presence of a catalyst. The disproportionately significant increase in the frequency of high energy collisions causes an increase in reaction rates as temperature rises.
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What is the water referred to as in a solution of a carbonated beverage
Answer: It is described as a solvent
Explanation: I hope this helps!
Answer the following questions about two possible reaction mechanisms for the same reaction.
Determine the overall balanced equation.
What is the role of E2X2 in the reaction mechanism? Explain your reasoning.
Explain why Reaction Mechanism 1 is less likely to occur in terms of the collision theory.
For Reaction Mechanism 2, determine the rate law of the reaction based on the rate determining step of the reaction mechanism
An elimination reaction having two possible reaction mechanisms i.e, E₁ and E₂ mechanisms.
It is a type of reaction which is mainly used to transform saturated compounds (organic compounds which contains only single C-C bonds) to unsaturated compounds (compounds which feature double or triple carbon-carbon bonds).
Mechanism of elimination reaction: 1) Removal of proton 2) Formation of C-C pi bond 3) Removal of leaving group.
E₁-Reaction: It s also known as unimolecular elimination, They are having two steps-ionization and deprotonation. During the ionization, there is a formation of carbocation as an intermediate. In deprotonation, a proton will be lost by the carbocation. This will happen in the presence of a base which further leads to the formation of a pi-bond in the molecule. It exhibits first-order kinetics.
E₂-Reaction: E₂ mechanism refers to bimolecular elimination which is basically a one-step mechanism. Here, the C-H as well as carbon-halogen bonds mostly break off to form a new double bond. However, in E₂ mechanism, a base is the part of the rate-determining step. The reaction rate is mostly proportional to the concentrations of both the eliminating agent as well as the substrate. It exhibits second-order kinetics.
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Garima observed that when she left her tightly capped bottle full of water in the open sunlight, tiny bubbles were formed all around inside the bottle. She was amazed and asked about this phenomenon to her science teacher.
Answer:
Air dissolved in the water escapes in the form of tiny bubbles because the sun was giving heat energy to the bottle.
Explanation:
When water is boiled, the heat energy is transferred to the molecules of water, which begin to move more quickly. Eventually, the molecules have too much energy to stay connected as a liquid. When this occurs, they form gaseous molecules of water vapor, which float to the surface as bubbles and travel into the air.
Hot lead with a mass of 200. 0 g of (Specific heat of Pb = 0. 129 J/g˚C) at 176. 4˚C was dropped into a calorimeter containing an unknown volume of water. The temperature of the water increased from 21. 7˚C to 56. 4˚C. What mass of water is in the calorimeter?
The mass of water in the calorimeter is 7.98 g when The temperature of the water is increased from 21. 7˚C to 56. 4˚C.
We can use the equation Q = mcΔT to calculate the heat transfer between the lead and the water.
Q is the heat transfer, m is the mass of the substance, c is the specific heat of the substance, and ΔT is the change in temperature.
The heat absorbed by the water is equal to the heat lost by the lead, so we can set the two heat transfer equations equal to each other:
Qwater = Qlead
mwater * cwater * ΔTwater = mlead * clead * ΔTlead
where mwater is the mass of the water, cwater is the specific heat of water (4.184 J/g°C), ΔTwater is the change in temperature of the water, mlead is the mass of the lead (200.0 g), and ΔTlead is the change in temperature of the lead (176.4°C - 21.7°C = 154.7°C)
We can solve for mwater by isolating it on one side of the equation:
mwater = (mlead * clead * ΔTlead) / (cwater * ΔTwater)
mwater = (200.0 g * 0.129 J/g°C * 154.7°C) / (4.184 J/g°C * 35.7°C)
mwater = 7.98 g
So the mass of water in the calorimeter is 7.98 g.
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Class Set
When 4 mols of magnesium and 7.5 mols of oxygen gas react, how many grams of magnesium oxide will be
formed? What is the limiting reactant? What reactant is in excess?
2 Mg +022 MgO
The reactant is in excess 2Mg + O2 → 2MgO 4.8 g Mg ≡ 0.2 mole 3.2 g O2 ≡ 0.1 mole.
What is the limiting reactant?
The limiting reactant determines the maximum amount of product that can be formed from the reactants when reactants are not present in stoichiometric quantities .
The limiting reactant (or limiting reagent) is the reactant that gets consumed first in a chemical reaction and therefore limits how much product can be formed.The reactant that is consumed first and limits the amount of product(s) that can be obtained is the limiting reactant. To identify the limiting reactant, calculate the number of moles of each reactant present and compare this ratio to the mole ratio of the reactants in the balanced chemical equation.
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The reactants that are in excess 2Mg + O2 → 2MgO 4.8 g Mg ≡ 0.2 mol 3.2 g O2 ≡ 0.1 mol.
What is limiting reactant?The limiting reactant determines the maximum amount of product that can form from the reactants when the reactants are not present in stoichiometric amounts.The limiting reactant (or limiting reagent) is the first reactant consumed in a chemical reaction, thus limiting the amount of product that can be produced.A reactant that is consumed first and limits the amount of product obtained is a limiting reactant. To identify the limiting reactants, calculate the number of moles of each reactant present and compare this ratio to the molar ratio of the reactants in the balanced formula.A limiting reactant in a chemical reaction is a reactant that is completely consumed. When that reactant is gone, the reaction will not proceed. Therefore, it limits the reaction to the sequel. Excess reagents are reactants that could continue to react if other reagents had not been consumed.To learn more about limiting reactant from the given link:
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A phylogenetic tree constructed from gene sequence data is based on similarities in:
A) biochemical pathways.
B) ecological and habitat similarities.
C) morphology.
D) nucleotide substitutions in homologous genes.
E) patterns of embryological development.
A phylogenetic tree constructed from gene sequence data is based on similarities in, the correct option is (D) nucleotide substitutions in homologous genes.
Phylogenetic tree are constructed from gene sequence data by comparing the sequences of homologous genes (genes that have a similar function and evolutionary origin) from different organisms. The similarities and differences in the nucleotide sequences of these genes are used to infer evolutionary relationships among the organisms. The tree is built based on the principle of common descent, which states that organisms that share a common ancestor will have more similar gene sequences than those that do not. By comparing the sequence similarities and differences, it is possible to infer the evolutionary relationships among different organisms and construct a branching diagram, known as a phylogenetic tree, that illustrates these relationships.
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During the light reactions water is oxidized to O2. Where do the hydrogens go?
A. Used in the reduction of NADP+
B. Used in the synthesis of ATP by chemiosmosis
C. Diffuse out of the chloroplast and unite with O2 to form H2O
D. A and B
E. A, B and C
During the light reactions water is oxidized to O2. hydrogen go to Used in the reduction of NADP+.
The photolysis process, sometimes referred to as the light reaction, occurs when light is present. Typically, it occurs in the chloroplasts' grana. Pigment molecules are present in photosystems. One of the key pigments in plants that actively participates in light-related processes like photosynthesis is chlorophyll. In the chloroplast of the mesophyll cells of the leaves, a light-dependent process takes place. The stacked disc-like structures known as thylakoids make up the double-membraned cell organelles known as chloroplasts. The membrane of these thylakoids contains the pigment chlorophyll, which is necessary for the process and is where the light reaction takes place.
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in a reaction of an acid that has an equal amount of a base, the ph changes to a value that is closer to
In a reaction of an acid that has an equal amount of a base, the ph changes to a value that is closer to 7 or neutral .
Any solution is considered "neutral" and has a pH of 7 if there is an equal quantity of acid and base present. Because the pH of the neutralised substance is close to or equal to 7, when an acid combines with a base, acid and water are produced. The autoprotolysis reaction, the next equilibrium, serves as the foundation for acid-base behaviour in water.
Reactions to neutralisation, when a strong acid and a strong base are mixed together in the right amounts, [H+] equals [OH], creating a neutral solution with pH of 7, the outcome is. Acidic and basic qualities are no longer existent because the acid and base have neutralised one another. When acid and base are together, a neutralisation reaction occurs where salt and water are created.
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3. Give an example of where a scientist might be: a. accurate but not precise. b. precise but not accurate. c. both precise and accurate.
Give an example of where a scientist might be: a. accurate but not precise. b. precise but not accurate. c. both precise and accurate, are listed below.
What is accurate?
Accuracy is the measure of how closely a measurement resembles the actual or accepted value. How closely two measurements of the same thing differ is referred to as precision.
What is precise?
The precision of an object is defined as the similarity between two or more measurements. If you weigh an object five times and it weighs 2 kg each time, the measurement has precision but not necessarily accuracy, or it might be the other way around.
Therefore, Give an example of where a scientist might be: a. accurate but not precise. b. precise but not accurate. c. both precise and accurate, are listed below.
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a. Accurate but not precise:
An example of a scientist being accurate but not precise could be a situation where a scientist measures the boiling point of a substance and obtains a series of measurements consistently close to the accepted value but with a wide range of variation among the measurements. Although the measurements may not be precise (due to the variability), they are accurate because they are close to the true value.
b. Precise but not accurate:
An example of a scientist being precise but not accurate could be a scenario where a scientist uses a faulty instrument to measure the length of an object. The measurements obtained may consistently show the same value (high precision) but differ significantly from the actual length (low accuracy). In this case, the measurements are precise (consistent) but not accurate (far from the true value).
c. Both precise and accurate:
An example of a scientist being both precise and accurate could be a situation where a scientist measures the weight of an object using a highly calibrated and accurate weighing scale. The scientist obtains several measurements that are all very close to each other (high precision) and also very close to the true weight of the object (high accuracy). In this case, the measurements are both precise and accurate, indicating a high level of reliability and validity.
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You expect to have 49.2 g of KCl but only make 37.5 g of KCl. What is the actual yield?
Strategy:
Use the mole ratio and find the number of moles of oxygen formed by 6 moles of potassium chlorate. 6 moles of KClO3 (735.3 grams of KClO3) produce 9 moles of O2 gas. Technically, this is the theoretical yield, but the answer becomes more useful when you convert moles to grams.
if a burst of light described above had a total energy of 4.50 kj, how many moles of electrons can be released
If a burst of light had a total energy of 4.50 kJ, it can release 0.0468 moles of electrons.
This number is calculated by dividing the total energy by the energy per mole of electrons, which is equal to the Faraday constant (96,485 C/mol). In this case, the answer is approximately 0.0468 moles of electrons.
The Faraday constant is a measure of the amount of electrical charge that is released when one mole of electrons is passed through an electrical circuit.
This constant is important because it allows us to calculate how many moles of electrons can be released when a certain amount of energy is present.
By dividing the total energy of 4.50 kJ by the Faraday constant, we can determine the number of moles of electrons that can be released.
Although a part of your question is missing, you might be referring to this question:
A burst of light is being emitted through a photon.
If a burst of light described above had a total energy of 4.50 kj, how many moles of electrons can be released?
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Which atom gives up its electrons most easily?
Answer: Caesium
Explanation:
Caesium has the lowest ionization energy. With the lowest ionization energy, it is the one that will most easily give up electrons.
Answer: cesium
Explanation:(cs)
what volume of a 0.45 m solution of hcl would just neutralize 210 ml of a solution containing 4.7 g of ba(oh)2 ?
Volume of the 0.45 m solution of HCl would just to neutralize 210 ml of a solution containing 4.7 g of the Ba(OH)₂ is 0.12 L.
The reaction is given as :
2HCl(aq) + Ba(OH)₂(aq) ---> BaCl₂(aq) + 2H₂O
1 mole of Ba(OH)₂ react with the 2 mole HCl
Molarity of HCl, C1 = 0.45 M
Volume of HCl, V1 =.?
The mass of Ba(OH)₂ = 4.7 g
Moles = mass / molar mass
Moles = 4.7 / 171.34
Moles = 0.027 mol
The moles of HCl = 2 × 0.027
= 0.054 mol
Volume = moles / molarity
Volume = 0.054 / 0.45
Volume = 0.12 L
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Which of the following statements is true about nuclear fission? 1Fission occurs most often naturally. 2Fission increases the mass of each nucleus involved. 3Fission produces nuclei that are more stable than the original nuclei. 4Fission is the primary process that produces energy in stars.
Natural fission can take place and generate more stable nuclei than the original nucleus.
What happens when a neutron collides with a bigger atom?When a neutron collides with a bigger atom, it causes it to excite and fragment into two smaller atoms, which are known as fission products. Additionally, additional neutrons are emitted, and these can start a chain reaction.
There is a great amount of energy produced when each atom divides.
Uranium and plutonium are most frequently employed in nuclear power reactors.
Fission is a nuclear reaction in which splitting of a nucleus into two daughter nuclei takes place.
Nucleus is the central positive body of the atom that consists of neutrons and protons.
Neutron is a subatomic particle with zero charge which is present in the nucleus of the atom.
A nuclear power reactor is a device that is used to initiate and control a nuclear fusion reaction chain.
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Would you expect an Olympic swimmer to need more or less food
energy every day than you do? Explain why.
Yes, an Olympic swimmer to need more food energy every day than we do.
Why do swimmers need energy?
Swimmers need energy to fuel their bodies for intense physical activity. Swimming is an anaerobic and aerobic exercise, both of which require energy to be used efficiently. Swimmers typically need to consume carbohydrates before and during their workouts for sustained energy, as well as protein to help their muscles repair and rebuild. Eating a balanced diet that is high in carbohydrates and proteins will help swimmers stay energized and perform their best.
An Olympic swimmer would need more food energy every day than the average person because they need more energy to train and compete. Swimming is an intense physical activity that requires a lot of energy and endurance. Olympic swimmers must swim for hours each day, working hard to reach their peak performance. As a result, they would need more food energy to fuel their bodies for the strenuous physical activity.
Therefore, an Olympic swimmer to need more food energy every day than we do.
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Which atmospheric gases absorb more than one type of light?
Carbon dioxide and methane are the atmospheric gases which absorbs more than one type of electromagnetic radiations or light.
What is electromagnetic radiation?The electromagnetic radiation consists of waves made up of electromagnetic field which are capable of propogating through space and carry the radiant electromagnetic energy.
The radiation are composed of electromagnetic waves which are synchronized oscillations of electric and magnetic fields . They are created due to change which is periodic in electric as well as magnetic fields.
In vacuum ,all the electromagnetic waves travel at the same speed that is with the speed of air.The position of an electromagnetic wave in an electromagnetic spectrum is characterized by it's frequency or wavelength.
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calculate the time it takes for the concentration of ab to reduce to 1/4 of its original concentration
For a first order reaction, the time taken to reduce the initial concentration by a factor of 1/4 is 10 min.
calculate the time it takes for the concentration of ab to reduce to 1/4 of its original concentration?
When volume is reduced by one fourth, then the concentration becomes 4 times. It is explained by the fact that concentration = number of moles/volume . And hence, concentration is inversely proportional to volume. So, when volume is reduced by one fourth, then the concentration becomes 4 times.t1/4 can be taken as the time taken for the concentration of a reactant to drop to 3/4 of its value. If the rate constant for a first order reaction is k, the t1/4 can be written as [ln2 = 0.695, ln = 1.1]By a factor of " can commonly mean the same as "multiplied by" or "divided by." If the variable x is increased by a factor of 4, it further becomes 4x. If the variable x is decreased by a factor of 4, then it becomes x/4.To learn more about concentration refers to:
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Which of the following statements is wrong about cathode rays?A.They travel in straight lines towards cathodeB.They produce heating effectC.They carry negative chargeD.They produce X-rays when strike with material having high atomic masses
The statements wrong about cathode rays is none of the given option. All the given option is true about the cathode rays.
The statements for the cathode rays is given as :
A. They travel in straight lines towards cathode. This statement is true about the cathode rays.
B. They produce heating effect. This statement is true about the cathode rays.
C. They carry negative charge. This statement is true about the cathode rays.
D. They produce X-rays when strike with material having high atomic masses. This statement is true about the cathode rays.
Thus, none of the option is incorrect about the cathode rays.
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2 nh3 3 cuo g 3 cu n2 3 h2o in the above equation how many moles of n2 can be made when 42 moles of cuo are consumed?
The balanced equation for the reaction is: 2 NH3 + 3 CuO ---> 3 Cu + 3 H2O + N2, when 42 moles of CuO are consumed, 14 moles of N2 can be made.
From this equation, we can see that for every 3 moles of CuO that are consumed, 1 mole of N2 is produced.
To find the number of moles of N2 that can be made when 42 moles of CuO are consumed, we can use the stoichiometry of the reaction. We can use the following formula:
moles of product = moles of reactant x (moles of product / moles of reactant)
In this case, we can use the following equation to find the number of moles of N2 that can be produced:
= moles of N2
= 42 moles x (1 mole N2 / 3 moles CuO)
= 14 moles of N2
So, when 42 moles of CuO are consumed, 14 moles of N2 can be made.
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we mixed 30 ml of 1.0 m hcl with 70 ml of 1.0 m naoh. what is the theoretical value for the temperature increase? express your answer in
The theoretical value for the temperature increase would be negligible, as the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH) is exothermic but also dilute.
When HCl and NaOH are mixed together, they react to form water and salt (sodium chloride). This reaction is exothermic reaction, which means it releases heat. However, because the solutions are dilute (1.0 M), the amount of heat released will be small and may not be measurable. Additionally, the heat released during the reaction would be quickly dissipated due to the small volume of the solutions. Thus, the theoretical temperature increase would be negligible.
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Your question seems incomplete, but I suppose the question was:
"we mixed 30 ml of 1.0 m hcl with 70 ml of 1.0 m naoh. what is the theoretical value for the temperature increase?"
solvent choice is an important factor in planning a synthesis. which solvent(s) below can be used to generate this and only this product?
The solvents used to generate this and only this product are DMF, DMSO, i-PrOH.
1-bromopropane reacts with sodium propan-2-olate to form 1-isopropoxypropane. The mechanism of this reaction follows SN2 pathway.
Polar aprotic solvents like DMF, DMSO favors SN2 reaction and provides an ease to carry the reaction.
If the nucleophile is dissolve in less polar solvent, then SN2 reaction goes faster to form required product.
The nucleophile sodium propan-2-olate is dissolve in less polar solvent i-propanol (i-PrOH).
Thus, the solvents used to generate the only product are shown below:
DMF (dimethyl formamide)
i-PrOH (iso-propanol)
DMSO (dimethyl sulfoxide)
The synthesis reaction is given in the image.
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Element X has 30 protons and is known to exist as 3 isotopes. One isotope is 56.5% abundance and has 38 neutrons. Another isotope is 23.4% and has 39 neutrons. The other isotope is 20.1% and contains 40 neutrons. What is the average atomic mass?
i’ll give brainliest
Answer:
The average atomic mass of element X is 68.719 amu
Step-by-step explanation:
1. To determine the average atomic mass of element X, the atomic masses and abundances of its isotopes must be used.
2. The atomic mass of the first isotope is 68 amu, the second isotope is 69 amu, and the third isotope is 70 amu.
3. To calculate the average atomic mass, the formula is used: Average Atomic Mass = (68amu x 0.565) + (69amu x 0.234) + (70amu x 0.201)
4. Applying the formula, the average atomic mass of element X is 68.719 amu.
The rate of the reaction was studied at a certain temperature. O(g) + NO2(g) NO(g) + O2(g) (a) In the first set of experiments, NO2 was in large excess, at a concentration of 1. 0 ✕ 1013 molecules/cm3 with the following data collected. Time (s) [O] (atoms/cm3) 0 5. 0 ✕ 109 1. 0 ✕ 10-2 1. 9 ✕ 109 2. 0 ✕ 10-2 6. 8 ✕ 108 3. 0 ✕ 10-2 2. 5 ✕ 108 What is the order of the reaction with respect to oxygen atoms? zero order half order first order second order third order Correct: Your answer is correct. (b) The reaction is known to be first order with respect to NO2. What is the overall rate law? chemPadHelp rate = k. [O]. [NO2] rate = k. [O]. [NO_2] Correct. Determine the value of the rate constant. WebAssign will check your answer for the correct number of significant figures. 3 100. 15 Incorrect: Your answer is incorrect. Cm3/molecules·s
The value of rate constant is 3.33 x 10^-11 cm3/molecules-s. To determine the order of the reaction with respect to oxygen atoms, we can use the data collected in the first set of experiments.
Where NO2 was in large excess. We can use the method of initial rates, where we compare the rates of the reaction at different initial concentrations of O. From the data, we can see that
at t = 1.0 x 10^-2 s, [O] = 1.9 x 10^9 atoms/cm3 and
the rate is k[O]^x[NO2]
, where x is the order of the reaction with respect to O.
At t = 2.0 x 10^-2 s,
[O] = 6.8 x 10^8 atoms/cm3 and
the rate is k[O]^x[NO2].
At t = 3.0 x 10^-2 s,
[O] = 2.5 x 10^8 atoms/cm3 and
the rate is k[O]^x[NO2].
Since the order of the reaction with respect to O is x. for
(b), the reaction is known to be first order with respect to NO2,
so the overall rate law is rate = k[NO2].
To determine the value of the rate constant, we can use the integrated rate law, which is -[O] = kt + [O]0,
Where [O] is the concentration of O at time t,
k is the rate constant and
[O]0 is the initial concentration of O.
Using the data from the first experiment
where t = 3.0 x 10^-2 s and
O] = 2.5 x 10^8 atoms/cm3,
the value of k. -2.5 x 10^8 = k * 3 x 10^-2 + 5 x 10^9.
Solving for k, we get k = 3.33 x 10^-11 cm3/molecules-s.
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What important scientific tool did dmitri mendeleev invent?
Russian chemist Dmitri Mendeleev wrote down the symbols for the chemical elements on February 17, 1869, arranged them in numerical order based on their atomic weights.
and created the modern periodic table. One of history's most illustrious scientists, the Russian chemist Dmitri Mendeleev, passed away 100 years ago this year (1834–1907). His invention of the periodic table in 1869 was a major accomplishment that serves as both a helpful mnemonic and a tool for organizing all of chemistry. The elements were organized by Mendeleev in ascending order of relative atomic mass. He observed a periodic tendency in the chemical characteristics of the elements and their compounds as he performed this.There were no openings for newly found elements in his eight groupings of the elements. The structure for the contemporary periodic table was developed in 1869 by Russian scientist Dmitri Mendeleev, who left spaces for elements that had not yet been identified.
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which of the following compounds has the lowest normal boiling point? a. ch3ch2ch2f b. ch3ch2ch2nh2 c. ch3ch2ch2oh d. ch3ch(oh)ch3 e. ch3ch2cooh
Among the compounds listed, a) CH3CH2F has the lowest intermolecular forces, meaning it has the lowest boiling point.
This is because the fluorine atom has the smallest atomic radius, meaning it has the weakest dipole-dipole interactions.
The other compounds (CH3CH2NH2, CH3CH2CH2OH, CH3CH(OH)CH3, and CH3CH2COOH) all have higher boiling points due to the fact that they have larger atomic radii, resulting in stronger dipole-dipole interactions.
This is because the fluorine atom is the smallest in size and has the strongest intermolecular force, thus giving it the lowest boiling point.
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the atmospheric pressure on the surface of venus is 6.84 x 10^4 mmhg. calculate the atmospheric pressure in atm and torr. round your answer to 3 significant digits
The atmospheric pressure on the surface of Venus is 6.84 × 10⁴ mmHg in atm and torr is :
6.84 × 10⁴ mmHg = 0.67 atm6.84 × 10⁴ mmHg = 513 torrThe atmospheric pressure is given as:
Atmospheric pressure = 6.84 × 10⁴ mmHg
1 atm (atmospheric pressure) = 101325 pascal (Pa).
To convert the mmHg to atm , divide the pressure value by 101325.
Pressure in atm = 0.67 atm
1 Torr is equals to 133.322 Pa. divide the pressure value by 133.322 to convert it in torr.
Pressure in Torr =513.0 Torr
Thus, pressure in atm is 0.67 atm and the pressure in torr is 513 torr.
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A chemist fills a reaction vessel with 1. 32 atm chlorine (Cl) gas, 7. 56 atm phosphorus (PA) gas, and 3. 30 atm phosphorus trichloride (PCI) gas at a temperature of 25. 0°C. Under these conditions, calculate the reaction free energy Î"G for the following chemical reaction: +6Cl2gP4g reverseEquArrow. Gif 4PCl3g. Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoul
The Gibbs free energy ΔG for the following chemical reaction:
6Cl2 + P4 -> 4PCl3 is 82.764kJ
Given the pressure of chlorine gas (P1) = 1.32atm = 1.32 x 10^5Pa
The pressure of phosphorous gas (P2) = 7.56atm = 7.56 x 10^5Pa
The pressure of phosphorous trichloride (P3) = 3.30atm = 3.30x10^5Pa
The temperature of vessel containing these gases (T) = 25°C = 298K
We know that from Gibbs equation ∆ = ∆° + () here R is the universal gas constant = 8.314
∆ = ∆° + (P3^4/P1^6 x P2)
For equilibrium condition ∆ = 0
So, ∆° = (P3^4/P1^6 x P2)
∆° = -8.314x298 x 2.303 x log[(3.30x10^5)^4/(1.32 x 10^5)^6(7.56 x 10^5)]
∆° = -5.7 x 10^3log[118.5/39.91x10^15]
∆° = -5.7 x 10^3 x log[2.96/10^15]
∆° = -5.7 x 10^3 x (-14.52)
∆° = 82.764 x 10^3 = 82.764kJ
Hence the required Gibbs free energy is 82.764kJ
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What is the solubility of calcium sulfate (CaSO4) in 0. 30 M aqueous sodium sulfate (Na2SO4)? (Ksp of calcium sulfate = 2. 0 x 10^-5
The solubility product constant (Ksp) of calcium sulfate (CaSO4) and the idea of ion product may be used to determine the solubility of calcium sulfate (CaSO4) in 0.30 M aqueous sodium sulfate.
(Na2SO4). The calcium ion (Ca2+) concentration in the solution. may be estimated as follows: [Ca2+][SO42-] = Ksp [Ca2+][SO42-] = 2.0 x 10^-5 When there is sodium sulfate present, part of the sulfate ions will originate from the sodium sulfate rather than the calcium sulfate. The total sulfate ion concentration (SO42-) in the solution may be determined as follows [SO42-] = [Na2SO4] + [CaSO4] + x = 0.30 M (where x is the concentration of CaSO4) When we enter the values into the Ksp expression, we get: 2.0 x 10^-5 = [Ca2+] [0.30 M + x] x [0.30 M + x] = [Ca2+] x [0.30 M + x] [Ca2+] = (2.0 x 10^-5) / (0.30 M + x) We may substitute [Ca2+] in the Ksp equation since [Ca2+] = [CaSO4]: ([CaSO4])2 / (0.30 M + [CaSO4]) = 2.0 x 10-5 This equation may be solved for [CaSO4,] which yields the calcium sulfate solubility in 0.30 M aqueous sodium sulfate solution.
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which purpose is most used for tlc method?
a. Identification
b. Makes the eluent more polar
c. neutral or acid
d. slightly sour
Makes the eluent more polar is the correct option.this is the purpose which is most used for TLC method.TLC means thin-layer chromatography.
Non-volatile mixtures can be separated using the chromatography technique known as thin-layer chromatography (TLC). A sheet of an inert substrate, such as glass, plastic, or aluminum foil, is used for thin-layer chromatography. This substrate is covered with a thin layer of an adsorbent material, often silica gel, aluminum oxide (alumina), or cellulose. To elute more strongly retained solutes, an increase in eluent strength is necessary. RP-HPLC (raise organic, create more non-polar) (increase organic, make more non-polar). NP-HPLC (increase solvent to make more polar) (increase solvent to make more polar) For many separations, eluent strength gradients (gradual changes) are utilized. When polar compounds are induced to be more attracted to the mobile phase by a moderately polar eluent, the equilibrium shifts and the compound spends more time in the mobile phase, increasing the R f.
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