Calculate the standard biological Gibbs free energy for the reaction: pyruvate- + NADH + H+(aq) ---> Lactate- + NAD+ at 309 K given that the standard Gibbs free energy = -65.0 kJ/mol at this temperature. This reaction occurs under conditions of low oxygen supply, such as in muscle cells during strenuous exercise. Note: See Box 7.1 on page 164. The biological standard state has hydrogen ions at 1x10-7 molar instead of 1 M.

Answers

Answer 1

Answer:

[tex]-23592.19\ \text{J/mol}[/tex]

Explanation:

T = Temperature = 309 K

[tex]\Delta G^{\circ}[/tex] = Standard Gibbs free energy = -65.0 kJ/mol

R = Gas constant = 8.314 J/mol K

[tex][H^+][/tex] = Biological standard state has hydrogen ions = [tex]10^{-7}\ \text{molar}[/tex]

Reaction quotient is given by

[tex]Q=\dfrac{1}{[H^+]}\\\Rightarrow Q=\dfrac{1}{10^{-7}}\\\Rightarrow Q=10^7[/tex]

Standard biological Gibbs free energy is given by

[tex]\Delta G=\Delta G^{\circ}+RT\ln Q\\\Rightarrow \Delta G=-65000+8.314\times 309\times \ln10^7\\\Rightarrow \Delta G=-23592.19\ \text{J/mol}[/tex]

The standard biological Gibbs free energy of the reaction is [tex]-23592.19\ \text{J/mol}[/tex]


Related Questions

Which of these solutions are basic at 25 °C ? A:[OH−]=2.53×10−7 M B:[H3O+]=9.99×10−9 M C:[H3O+]=6.31×10−4 M

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Answer: frfg6

Explanation: 655tyyt

The process through which professional scientists evaluate the quality of each other’s research is called
group counsel.
group review.
peer counsel.
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Answer:

peer reveiw

Explanation:

Answer:

Peer review.

Explanation: Ask Edu

Which of the following increases with increasing atomic
number down a group?

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Answer:

The number of energy levels increases as you move down a group as the number of electrons increases. Each subsequent energy level is further from the nucleus than the last. ... The outermost electrons are repelled by the inner shell electrons (Screening effect) and hence, the atomic size increases.

Explanation:Increase in atomic size

why saturated fatty acid can’t create kink ?​

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Saturated fatty acids exhibit a linear structure while unsaturated fatty acids bend, or kink, due to double bonds within the chemical foundation.

17. Which is a fat-soluble vitamin?
O vitamin B
O vitamin C
O vitamin A

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vitamin A is the fat soluble

The atom is one of the basic units of matter. Which part of the atom mostly determines the size of the atom?
a.Electrons

b.Nucleus

c.Neutrons

d.Protons

Answers

Answer:

Atomic size is the distance from the nucleus to the valence shell where the valence electrons are located. The separation that occurs because electrons have the same charge. The number of protons in the nucleus. The core electrons in an atom interfere with the attraction of the nucleus for the outermost electrons.

Explanation:

That would be B I believe, but please correct me if I'm wrong.

which body system carries oxygen, glucose and amino acids to all the cells of the body?


Answers

Answer:

Blood

Explanation:

This flows through the body so it gives it all over.

The Circulatory System is responsible for transporting glucose, amino acids and oxygen to all the cells of the body

Which of the following elements has 3 electrons in the 2p sublevel?
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O B. C
O C. B
O DN

Answers

Answer:

the answer is D. N

AP3X

According to electronic configuration, there are 3 electrons in the 2p sublevel ,hence the correct option is D.

Electronic configuration is defined as the distribution of electrons that are present in an atom or molecule in  an atomic or molecular orbitals.It describes how each electron moves independently in an orbital.

Knowledge of electronic configuration is important for understanding the structure of periodic table. It helps in understanding the chemical properties of elements.

Elements undergo chemical reactions so as to achieve stability. Main group elements obey the octet rule in their electronic configuration while the transition elements follow the 18 electron rule. Noble elements have valence shell complete in  their ground state and hence are said to be stable.

Thus, the correct option is D.

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What mass in grams of MgSO4 is required to make 59.3 mL of 2.68 M
solution?

Answers

Answer:

Approximately [tex]19.1\; \rm g[/tex].

Explanation:

Number of moles of formula units of magnesium sulfate required to make the solution

The unit of concentration in this question is "[tex]\rm M[/tex]". That's equivalent to "[tex]\rm mol \cdot L^{-1}[/tex]" (moles per liter.) In other words:

[tex]c(\mathrm{MgSO_4}) = 2.68\; \rm M = 2.68\; \rm mol \cdot L^{-1}[/tex].

However, the unit of the volume of this solution is in milliliters. Convert that unit to liters:

[tex]\displaystyle V = 59.3\; \rm mL = 59.3 \; \rm mL \times \frac{1\; \rm L}{1000\; \rm mL} = 0.0593\; \rm L[/tex].

Calculate the number of moles of [tex]\rm MgSO_4[/tex] formula units required to make this solution:

[tex]\begin{aligned}n(\rm MgSO_4) &= c \cdot V \\ &= 2.68 \; \rm mol \cdot L^{-1} \times 0.0593\; \rm L \approx 0.159\; \rm mol \end{aligned}[/tex].

Mass of magnesium sulfate in the solution

Look up the relative atomic mass data of [tex]\rm Mg[/tex], [tex]\rm S[/tex], and [tex]\rm O[/tex] on a modern periodic table:

[tex]\rm Mg[/tex]: [tex]24.305[/tex].[tex]\rm S[/tex]: [tex]\rm 32.06[/tex].[tex]\rm O[/tex]: [tex]15.999[/tex].

Calculate the formula mass of [tex]\rm MgSO_4[/tex] using these values:

[tex]M(\mathrm{MgSO_4}) = 24.305 + 32.06 + 4 \times 15.999 \approx 120.361\; \rm g \cdot mol^{-1}[/tex].

Using this formula mass, calculate the mass of that (approximately) [tex]0.159\; \rm mol[/tex] of [tex]\rm MgSO_4[/tex] formula units:

[tex]\begin{aligned}m(\mathrm{MgSO_4}) &= n \cdot M \\&\approx 0.159 \; \rm mol \times 120.361 \; \rm g \cdot mol^{-1} \approx 19.1\; \rm g\end{aligned}[/tex].

Therefore, the mass of [tex]\rm MgSO_4[/tex] required to make this solution would be approximately [tex]19.1\; \rm g[/tex].

every spring has an equilibrium position which statement describe a spring at it equilibruim position?

Answers

The elastic potential energy is zero. The net force acting on the spring is zero. Explanation: The equilibrium position of a spring is the position that the spring has when its neither compressed nor stretched - it is also called natural length of the spring.Mar

Write the symbol for every chemical element that has atomic number less than 73 and atomic mass greater than 173.2 u

Answers

Look at the periodic table

How much heat would be required to convert 5.31 mol of a pure substance from a liquid at 40.0°C to a gas at 113.0°C?

Answers

Answer:

Q = 7.7 KJ

Explanation:

The complete question carries the following data:

Specific Heat Capacity of Liquid State = C(l) = 1.45 J/mol.°C

Specific Heat Capacity of Gaseous State = C(g) = 0.65 J/mol.°C

Boiling Temperature = Tb = 88.5°C

Heat of Vaporization = ΔH(vap) = 1.23 KJ/mol

Now, first we calculate the heat required (Q₁) to raise he temperature to boiling point:

Q₁ = n*C(l)*ΔT₁

where,

n = no. of moles = 5.31 mol

ΔT₁ = Temperature difference from 40°C to Tb = 88.5°C - 40°C = 48.5°C

Therefore,

Q₁ = (5.31 mol)(1.45 J/mol.°C)(48.5°C)

Q₁ = 373.4 J = 0.37 KJ

Now, we calculate the heat required (Q₂) to change its phase:

Q₂ = nΔH(vap)

Q₂ = (5.31 mol)(1.23 KJ/mol)

Q₂ = 6.53 KJ

Now, we calculate the heat required (Q₃) to raise he temperature to boiling point:

Q₃ = n*C(g)*ΔT₃

where,

n = no. of moles = 5.31 mol

ΔT₃ = Temperature difference from Tb to 113°C = 113°C - 88.5°C = 24.5°C

Therefore,

Q₃ = (5.31 mol)(0.65 J/mol.°C)(24.5°C)

Q₃ = 84.5 J = 0.08 KJ

So, the total heat required to convert 5.31 mol of this pure substance from a liquid at 40°C to a gas at 113°C is:

Q = Q₁ + Q₂ + Q₃

Q = 0.37 KJ + 6.53 KJ + 0.08 KJ

Q = 7.7 KJ

The total heat required to convert the pure substance from liquid to gas at the given temperature is 814 J.

The given parameters;

molar heat capacity of liquid, C(l) = 1.45 J/mol.⁰Cmolar heat capacity of gas, C(g) = 0.65 J/mol.⁰C

The total heat required to convert the pure substance from liquid to gas at the given temperature is calculated as follows;

[tex]Q = nc_l \Delta \theta + nc_g \Delta \theta \\\\ \Delta \theta = (113 - 40) = 73^0 C \\\\Q = (5.31 \ mol \times 1.45 \frac{J}{mol .\ ^0C} \times 73\ ^0C) + (5.31 \ mol \times 0.65 \frac{J}{mol .\ ^0C} \times 73 \ ^0C)\\\\Q = 814 \ J[/tex]

Thus, the total heat required to convert the pure substance from liquid to gas at the given temperature is 814 J.

"Your question is not complete, it seems to be missing the following information;"

How much heat would be required to convert 5.31 mol of a pure substance from a liquid at 40.0°C to a gas at 113.0°C? (molar heat capacity of liquid, C(l) is 1.45 J/mol.⁰C and molar heat capacity of gas, C(g) is 0.65 J/mol.⁰C).

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When given the following: density = 0.79 g/mL and mass =8g (answer can be found in your reading) What is the volume of the object?
HELP ASAP!!!!!!!!!!!!!

Answers

Answer:

V = 10.12 mL

Explanation:

Given that,

Density, d = 0.79 g/mL

Mass, m = 8 g

We need to find the volume of the object. Density is equal to the mass per unit volume. It can be given by :

[tex]d=\dfrac{m}{V}[/tex]

Where V is the volume of the object

[tex]V=\dfrac{m}{d}\\\\=\dfrac{8\ g}{0.79\ g/mL}\\\\V=10.12\ mL[/tex]

So, the volume of the object is 10.12 mL.

What mass of solute should you measure out in order to make 1,000 mL of a 0.3 M solution of magnesium phosphate Mg3(PO4)2?

Answers

Hey there !

Molecular Weight: 262.86 g/mol

Volume in liters : 1,000 mL => 1,000 / 1000 => 1 L

Number of moles of solution :

number of moles = volume x molarity

number of moles = 1 x 0.3  => 0.3 moles

Therefore:

1 mole Mg₃(PO₄)₂ ------------------- 262.86 g

0.3 moles ----------------------------- mass of Mg₃(PO₄)₂  ??

mass of Mg₃(PO₄)₂ = 0.3 x 262.86 / 1

mass of Mg(PO₄)₂ => 78.858 g

Hope this helps!

Which pattern on the periodic table is correctly predicted below?
Groups determine the number of valance electrons and periods determine the number of energy levels
Groups determine the number of energy levels and periods determine the number of valence electrons
Groups determine the number of protons, and periods determine energy levels
Groups determine the number of neutrons, and periods determine valence
Plzz

Answers

A.
Groups determine the number of valance electrons and periods determine the number of energy levels.

PLS help!!!!!!!!

Why are halogen atoms never a central atom?

Answers

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Answer:

They can’t have more than 8 valence electrons.

Explanation:

What's the molar mass of CoCl

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Answer:129.839 g/mol

Explanation:

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Table salt is a compound because Sodium (Na) and Chlorine (Cl) were combined to make a new group.

Will give brainliest, Look at the graph above. Compare it to the periodic table. What do you notice about the location on the periodic table of the elements that represent the high points

Answers

Answer:

We can see that the atomic radius decreases across every row.

Explanation:

I will comment more below.

The elements that represent the highest points on the graph are all elements of group 1 and occur at the head of the period to which they belong.

The periodic table is an arrangement of elements in groups and periods. The elements in the same group have the same number of valence electrons while the elements in the same period have the same number of shells.

Looking at the graph, we can see that the high points in the graph all correspond to the group 1 elements; sodium, potassium, rubidium and cesium.The have the highest atomic radii in the period. Atomic radii increases down the group but decreases across the period. Remember that these elements are at the head of the period to which they belong hence they have the highest atomic radii.

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Answers

Answer:

1. a

Explanation:

2. c

Answer:

1 is A number two is C

C is the element symbol for which element?
a. Carbon
b. Cadmium
c. Celenium
d. Chlorine​

Answers

Answer:

A) Carbon

Explanation:

the others are wrong its A

Answer:

A) carbon

Explanation:

carbon or simply c has an atomic number of 6 and it has an atomic mass of 12.01 amu. it belongs to group 4a

A rock rolls down a hill. Which form of energy is this an example of?

Chemical
Electrical
Mechanical
Thermal

Answers

Answer:

Mechanical

Explanation:

chemical

Explanation:

I took test 2020

which type of rection has the general formuial ab+cd

Answers

Double replacement. It is normally described as AB+CD=AD+CB.

Hope this helps!! (:
ABC-x8 because in 10th grade the formulaic start changing .


I need the answer multiple choice

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Answer:

it's answer is

element of an atom ✌️

PLEASEEEEEEEEE HELP WILL GIVE BRAINLIST

Which parts of the muscular and skeletal system work together to move muscles and bones?

arteries and vessels

tendons and ligaments

esophagus and intestine

nerves

Answers

Answer:

Tendons and ligaments

Explanation:

Tendons connect the skeletal system to the muscular system by attaching muscle to bone.

The ethyl acetate solution containing the mixture used in this experiment had a concentration of 20.0 g/L of benzoic acid. 1. Recovery of benzoic acid:

Answers

Answer:

The correct answer is "[tex]\frac{0.65}{V} \ percent[/tex]".

Explanation:

The given values are:

[tex]M_r=0.130 \ g[/tex]

[tex]M_o=20 \ g/L\times V(L)[/tex]

     [tex]=20 \ V[/tex]

As we know,

⇒ [tex]Recovery \ percent=\frac{Amount \ of \ substance \ recovered}{Amount \ of \ substance \ originally \ taken}\times 100[/tex]

On substituting the given values, we get

                                [tex]=\frac{0.130}{20 \ V}\times 100[/tex]

                                [tex]=\frac{0.65}{V} \ percent[/tex]

Note: percent = %

Is it A, B, C, or D?????
please help!!!!

Answers

Answer:

d

Explanation:

Answer:

Its d

Explanation:

Ik you already know this, I just wanted the points tbh

plzzzzz Plzzz Wil givr brainleast which type of weathering causes the mineral composition of rocks to change​

Answers

Chemical weathering.

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Chemical weathering works through chemical reactions that cause changes in the minerals.

Answer:

Chemical

Explanation:

Cause it is

How and why was the periodic table set up?

Answers

in a series of columns, or groups, and rows, or periods.
The person above me is 100% correct!!

PLEASE HELP !!!!!!!!!!!!!!!!!!!!!!!!!!!!!
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b thermal energy
c potential energy
d none of the above

Answers

Answer:

Explanation:

Potential energy

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